| Title |
Kaolinic clay derived PCDD/Fs in the feed chain from a sorting process for potatoes |
| Published in |
Chemosphere, Vol. 78, No. 2, p.99-105. ISSN 0045-6535. |
| Author |
Hoogenboom, L.A.P.; Zeilmaker, M.; Eijkeren, van J.; Kan, K.; Mengelers, M.; Luykx, D.M.A.M.; Traag, W.A. |
| Date |
2010 |
| Language |
English |
| Type |
article |
| Abstract |
At the end of 2004, during a routine monitoring project, high levels of PCDDs in milk from two farms were found. Using a bioassay and the congener patterns obtained by HRGC/HRMS, the source was traced back to the use of kaolinic clay for sorting potatoes in a production process of French fries. Rest products, especially peelings after scrubbing, were used as feed for dairy cows. Levels of PCCD/Fs in this product amounted to 44 ng WHO1998-TEQ kg(-1) (88% dw). The maximum level observed in milk was 20 pg WHO1998-TEQ g(-1) fat. A Physiologically Based PharmacoKinetic (PB-PK) model was used to model three data obtained before eliminating the source in order to estimate the starting time of the contamination of the cows, the steady-state level after prolonged contamination and the kinetics of the decrease in the levels after removal of the source. Samples of milk were continuously collected for several months showing a decrease to levels below the product limit of 3 pg WHO1998-TEQ g(-1) fat within 2 months, in excellent agreement with the decrease predicted by the PB-PK model. Different batches of clay were sampled and analysed, showing varying levels of especially PCDDs. All clays were confirmed to be kaolinic clay using X-ray analysis. Other by-products used for animal feed were also contaminated and led to precautionary measures at a few hundred farms, especially pig farms. However, levels in other animal derived products like pig meat did not exceed the product limits. (C) 2009 Elsevier Ltd. All rights reserved. |
| Publication |
http://library.wur.nl/WebQuery/wurpubs/407388 |
| OpenURL |
Search this publication in (your) library |
| Persistent Identifier |
urn:nbn:nl:ui:32-407388 |
| Metadata |
XML |
| Repository |
Wageningen University & Research Centre |